PhD offer (ECP group) – Biobased Acids-homoCYSteine Thiolactone-based monomers for new generation superabsorbent polymers (BACYST)

The ECP group is looking for a candidate for a thesis grant on the following topic:

“Biobased Acids-homoCYSteine Thiolactone-based monomers for new generation superabsorbent polymers (BACYST)”

Duration : 

36 month, starting in October 2024

Requested profile and qualifications : 

– Student with a master or engineer school degree with training in the field of macromolecular chemistry.
– Interest in the development of sustainable synthetic procedures
– Good communication, laboratory and organization skills
– Skills in written and spoken English is highly recommended.

Application: 

Send CV and motivation letter

Contact : Nicolas ILLY (e-Mail)

Project overview :  

Download PhD offer

Figure 1: Vue artistique d’un superabsorbant vert généré par IA

This research project aims to explore bio-based and biodegradable alternatives prepared according to more sustainable manufacturing processes in order to mitigate the environmental impact. To achieve this, a family of 100% bio-based superabsorbents polymers will be synthesized from abundant renewable compounds, such as itaconic acid, homocysteine thiolactone, chitosan polysaccharide or citric acid. Three different synthesis strategies based on a 100% atom efficient “click chemistry” concept will be developed resulting in different architectures and properties.

A particular attention will be paid to ensure that the syntheses are carried out under sustainable conditions (green solvent, room temperature and atmospheric pressure). Physico-chemical properties of the SAP hydrogels will be determined, in particular the biodegradability, the liquid absorption capacity and the mechanical strength of the hydrated product. The materials synthesized are designed to meet a strong social and regulatory demand. The synthesized materials would meet a strong societal and regulatory demand, and therefore have a high potential for industrial development.

Keywords: (macro)molecular chemistry, macromolecular engineering, hydrogels, green chemistry, biobased superabsorbent polymers