Four-electron reduction of CO2: from formaldehyde and acetal synthesis to complex transformations The expansive and dynamic field of CO2 Reduction Reaction (CO2RR) seeks to harness CO2 as a sustainable carbon…
Novel heteroleptic copper(i) complexes merging the chelating 1,2-bis-diphenyldiphosphine and various L^X type coligands Three novel heteroleptic mononuclear copper(I) complexes with a chelating diphosphine 1,2-bis-diphenylphosphinobenzene ligand (dppb) and various monoanionic bidentate…
Voltammetric techniques for low-cost on-site routine analysis of thymol in the medicinal plant Ocimum gratissimum The composition of essential oils varies according to culture conditions and climate, which induces a need for simple…
Research progress of fullerenes and their derivatives in the field of PDT © GOBS In contemporary studies, the predominant utilization of C60 derivatives pertains to their role as photosensitizers or agents…
Light-Induced, Structural Matrix Guided Stepwise Spin-State Switching in 3d-5d Molecular Assembly © IPCM A new iron(II) molecular complex {[W(CN)8][Fe(bik*)3]2}BF4·7H2O·1.5CH3OH (1.7H2O·1.5CH3OH) was synthesized using a versatile octacyanotungstate(V) building block and N-donor…
Halide-free CO2 cycloaddition onto styrene oxide catalysed by first row transition-metal derivatives of polyoxotungstates © E-POM Quaternary ammonium salts of metal derivatives of polyoxometalates [XW11O39M(H2O)]n- (X = P, Si; M…
© IPCM We report the synthesis and luminescent properties of a rare copper(I) alkynyl complex assembled from the diphosphane bis-diphenyphosphinobenzene (dppb) and phenylacetylide ligands with an extremely short Cu(I)⋯Cu(I) separation. The…
1H-1,2,3-triazolyl-1,6-naphthyridin-7(6H)-ones as Potential Fluorescent Nucleoside Analogues: Synthesis and Optical Properties In this article, we present the synthesis and the optical properties of three original molecules as potential fluorescent ribonucleoside analogues…
Silylation of Allylic C(sp3)–H Bonds Enabled by the Catalytic Generation of Allylpotassium Complexes Allylsilanes have long been recognized as key molecular building blocks in organic synthesis that are routinely employed…
Blue-Light Induced Iron-Catalyzed Synthesis of γ,δ-Unsaturated Ketones A cyclopentadienone iron tricarbonyl complex, able to harvest light and catalyze both dehydrogenation and reduction, allows the synthesis of γ,δ-unsaturated ketones using the…